PLUTON SOURCE AND EMPLACEMENT PROCESSES REVEALED BY PETROCHRONOLOGY OF SIERRAN DETRITAL TITANITE
Trace-element plots yield at least two interesting trends:
1) a bimodal distribution of Th/U. Older samples tend to have low Th/U, with some high values, whereas younger samples tend to have high Th/U, with a moderate amount of low values. Grains with low Th/U also have low Zr, La, and Sr. We interpret this bimodality to reflect the difference between two types of titanite crystallization (local scale): i) sub-solidus crystallization, possibly at the expense of ilmenite or through hydrothermal alteration and ii) primary igneous growth. The change from one dominant style of crystallization to another signifies changes in a more regional scale, possibly in the source, thermal history, etc.. Parallels can be drawn with titanite from other regions such as western Norway, where Precambrian igneous titanite is characterized by high Th/U and high Zr, whereas Caledonian metamorphic titanite (re)crystallization is typically low in Th/U and Zr.
2) Transition metals (Cr, V) decrease monotonically from ca. 120–100 Ma, and then again from ca. 96–88; variability also decreases over time. These trends likely show shifts in the source between the YVIS and TIS, and changes in the source during continued emplacement over shorter time periods. This trend is not obviously seen in the whole rock data, but mimics the Hf isotopic data in zircons from the same separates. Taken together age + TE data in titanite can provide insight into a number of processes occurring over a variety of scales.