GEOCHEMICAL CHARACTERIZATION OF TUOLUMNE INTRUSIVE SUITE ZIRCON, SIERRA NEVADA BATHOLITH, CALIFORNIA
Our results identify key differences between zircon from earlier and later TIS units. 95–92 Ma zircon from the Kuna Crest granodiorite (KC) sampled from Tuolumne Meadows and 92–90 Ma zircon from the equigranular Half Dome granodiorite (eHD) sampled from Tenaya Canyon display progressively increasing Hf, U/Yb, and decreasing Ti with date, consistent with crystallization of a progressively fractionated magma over a temperature range of ~830–675°C (assuming a[TiO2] = 0.7). In contrast, 90–86 Ma zircon sampled from Rafferty Creek, potentially derived from porphyritic Half Dome granodiorite, Cathedral Peak granodiorite, and/or Johnson Peak granite, are characterized by higher U/Yb and lower Ti, indicative of crystallization at 675–625°C, but with lower Hf relative to eHD. Many grains from Rafferty Creek sand display core–rim textures, with core dates and geochemistry characteristic of older KC or eHD zircon. A small subset of the Rafferty zircon have ~86 Ma cores with low Hf, low U/Yb, and high Ti, suggesting initial crystallization in hot (800–750°C), less evolved magma. Higher U/Yb and distinctly lower Hf in zircon younger than 90 Ma requires processes capable of enriching the Zr/Hf of TIS magmas at near-solidus temperatures. Together with previously published whole-rock geochemistry, these results place new constraints on the evolution of TIS magmas, and provide a foundation for future zircon geochemistry investigations designed to refine models for the formation and emplacement of the TIS.