GEOCHEMICAL INVESTIGATION OF THE LONG ISLAND CREEK GNEISS: IMPLICATIONS FOR THE PALEOZOIC TECTONICS OF THE SOUTHERN APPALACHIANS
The geochemistry of these samples reveal a probable igneous protolith with a granite to granodiorite composition. Discrimination diagrams show that half of these samples are A-type granites and the other half have an island arc signature. Samples of LICG from within the Brevard Zone are silicified (75.4 – 92.5 wt% SiO2), and all LICG samples south of the Brevard Zone have >70 wt% SiO2. In contrast, LICG samples obtained north of the Brevard Zone have a larger range in SiO2 (66.5 – 77.4 wt% SiO2), with the lower silica samples <70 wt% SiO2 having elevated Al2O3, Fe2O3, MgO and CaO. The lower silica samples also have higher concentrations of Ba, Sr, Co and Ni, consistent with less evolved compositions that may result from crystal accumulation within the magma chamber. Based on the aluminum-saturation index (ASI), and the modified alkali-lime index (MALI) by Frost and Frost (2008), the LICG samples from within and south of the Brevard zone are all peraluminous, and calc-alkalic, alkali-calcic, or calcic; all of these samples are also ferroan. Samples from north of the Brevard Zone have the same ASI and MALI classifications, but a few of the samples are magnesian.
Based on detailed geologic mapping by Crawford and Kath (2015), mineralogy and shear stress indicators of LICG samples (Hanson et al., 2019), and geochemical analysis, the Long Island Creek Gneiss pre-dates the latest motion of the Brevard Zone (~317 Ma), confirming that the Brevard Zone is not a major terrane boundary.