LONG-TERM CHEMICAL WEATHERING RATES IN THE PERIGLACIAL PIEDMONT PHYSIOGRAPHIC PROVINCE OF SOUTHEASTERN PENNSYLVANIA: WATERSHED GEOCHEMICAL MASS-BALANCE, SAPROLITIZATION RATES, AND EVIDENCE FOR A MODERN SAPROLITE
The small (21.4 ha) Brubaker Run watershed is located in periglacial southeastern Pennsylvania and contains saprolite developed on a muscovite-chlorite schist of the Lower Paleozoic Octoraro Formation. Long-term (103-105 year) mineral weathering rates have been calculated for the Brubaker Run watershed using total denudation rates derived from 10-beryllium data. The long-term average rates at which the weathering front has penetrated the bedrock (the saprolitization rate) are 4.5 m/My and 6.1 m/My for chlorite and muscovite, respectively. These measured long-term average saprolitization rates compare very favorably with published theoretical values for the nearby northern Maryland Piedmont which range from 2.2 to 5.3 m/My. Furthermore, at such saprolitization rates, the entire 3 m thickness of saprolite found in the Brubaker Run watershed could have formed within the last 700,000 years.
Preliminary present-day elemental stream solute flux values for Brubaker Run are approximately a factor of two higher than the long-term average losses. These observations support the hypothesis that the saprolite is forming at the present time, but at a higher chemical weathering rate relative to that of glacial times. Therefore, saprolite of southeastern Pennsylvania is not likely a relict weathering profile of Tertiary age.