FLUID INCLUSION EVIDENCE OF THE TRANSITION FROM LIQUID- TO VAPOR-DOMINATED RESERVOIR CONDITIONS IN THE NORTHWEST GEYSERS GEOTHERMAL FIELD, CALIFORNIA
Veins cutting the biotite hornfels record high-temperature, low-pressure contact metamorphism, an earlier liquid-dominated hydrothermal system and the transition from a liquid-dominated to the current vapor-dominated regime. The veins contain early biotite (± clinopyroxene, amphibole, tourmaline and apatite); this assemblage is overprinted by quartz (± actinolite and plagioclase) and late stage Fe>Zn-Cu sulfide minerals (± chlorite and quartz). Fluid inclusions have been studied in core samples from two wells in the northwest field located ~3.5 km apart, Prati-5 St-1 and L’Esperance-2. Both saline liquid-rich fluid inclusions containing up to 14 solid phases at room temperature, and vapor-rich inclusions are common in vein quartz. These fluid inclusion assemblages are interpreted to record the boiling off of the early liquid-dominated system. Energy dispersive spectroscopy analyses of the residues from decrepitated inclusions indicate the liquids were enriched in Cl, Na, Ca, Fe, K, F and potentially Mn, C, B, S and P. Modern measured temperatures fall within the range of total fluid inclusion homogenization temperatures (Th(tot)). In Prati-5, the maximum measured temperature is 314oC and Th(tot) range from 298 to 386oC. In L’Esperance-2, the maximum measured temperature is 296oC and Th(tot) range from 255 to 353oC. These temperature relationships may indicate that the transition from liquid-dominated to vapor-dominated conditions is relatively recent, and/or that temperatures in the Northwest Geysers have been relatively stable since quartz deposition.