GSA Annual Meeting in Indianapolis, Indiana, USA - 2018

Paper No. 185-4
Presentation Time: 9:00 AM-6:30 PM

A STRATIGRAPHIC MULTI-PROXY COVARIATION TEST FOR THE CAUSE OF THE LATE DEVONIAN PUNCTATA EVENT CARBON ISOTOPE EXCURSION, GUILMETTE FORMATION, EASTERN NEVADA, U.S.A


PERRY, Amelia A.1, LAMASKIN, Todd A.1, SCHANTZ, Krysden A.1, KOSTER, Olivia A.1, NOLAN, Jack T.1, ELLWOOD, Brooks2, LANE, Chad S.1 and OVER, D. Jeffrey3, (1)Department of Earth and Ocean Sciences, University of North Carolina Wilmington, 601 South College Rd., Wilmington, NC 28403, (2)Department of Geology and Geophysics, Louisiana State University, E-235 Howe-Russell, Baton Rouge, LA 70803, (3)Geological Sciences, SUNY-Geneseo, 1 College Circle, Geneseo, NY 14454

The Late Devonian “punctata event” represents one of the largest carbon isotope excursions in the Phanerozoic Eon, yet the cause of this carbon-cycle perturbation is unknown. To better understand the causes of the punctata event, and of carbon isotope excursions in general, we applied a multi-proxy approach using whole rock stable inorganic carbon isotopes (δ13Ccarb), magnetic susceptibility (MS), and major- and trace-element composition on shallow-marine carbonates of the Guilmette Formation in eastern Nevada that span the falsiovalis through punctata (FZ 1–5) conodont zones (Early–Middle Frasnian). Our record shows at least ten shifts in δ13Ccarb values depending the scale of observation used. In particular, a +4.5‰ shift occurs in the transitans (FZ 4) conodont zone followed by a –3‰ shift at the beginning of the punctata (FZ 5) conodont zone. A stepped +4‰ positive excursion in the punctata zone leads to the most positive values recorded, which then fall in a stepped fashion by 6‰ up to the stratigraphic level of the Alamo impact breccia (~mid-punctata zone). Since d13Ccarb is typically considered to be a proxy for surface-water productivity with more positive values representing greater burial of 12C-enriched organic carbon and because surface-water productivity (and positive δ13Ccarb values) can be driven by input of limiting nutrients, we hypothesize that increased δ13Ccarb values will co-vary with increases in proxies that represent aeolian and siliciclastic influx. MS is widely interpreted as a proxy for an influx of aeolian-derived detritus and concentrations of Ti, Fe, and Zr are proxies for the influx of siliciclastic material. Our records show that δ13Ccarb both co-varies and is anti-correlated with MS and major- and trace-element concentrations. Values of d13Ccarb follow opposite trends as MS, Fe, Ti, and Zr in the lower half of the record, which is dominated by deeper-water, catch-up sequences, suggesting that during third-order transgressions, influx of limiting nutrients does not govern surface-water productivity. In contrast, MS, Fe, Ti, and Zr values co-vary with δ13Ccarb in the upper-half of the record, dominated by shallower-water, keep-up sequences, suggesting a limiting nutrient control on δ13Ccarb during third-order highstand and associated progradation.