GSA Annual Meeting in Indianapolis, Indiana, USA - 2018

Paper No. 185-5
Presentation Time: 9:00 AM-6:30 PM

USING PERMIAN BRACHIOPOD SHELL STABLE ISOTOPES TO DETERMINE MID-TO-HIGH LATITUDE SEASONALITY


DEPUGH, Meagan E., Department of Geology and Geophysics, Texas A&M Univeristy, 3115 TAMU, College Station, TX 77843 and GROSSMAN, Ethan L., Department of Geology & Geophysics, Texas A&M University, College Station, TX 77843

Stable isotope paleothermometry capitalizes on the relationship between δ18O values found in carbonate or phosphate materials, δ18O values of seawater (δ18Ow), and seawater temperature to produce accurate paleotemperature records. However, this useful paleothermometer is limited by the mineral’s δ18O co-dependence on both the temperature and δ18O of the environmental waters from which the mineral precipitated. When studying temperatures of climates long past, the data are further complicated by the increased potential for burial and diagenesis.

This study presents high-resolution snapshots of the seasonal ranges in δ18O values found in Late Carboniferous to Permian, mid to high latitude, brachiopods. To do so, δ18O and δ13C data were generated by serially sampling pristine, nonluminescent brachiopod shells from South America, Arctic Canada, West Spitsbergen, and Western Australia. Samples were examined in thin section and cathodoluminescence to determine preservation and were milled along visible growth-associated banding. The resulting δ18O records exhibited systematic, cyclic variation across the specimen which is interpreted as seasonal changes in the environmental conditions over the lifetime of the shell. δ18O values average -0.32‰, and are more positive compared with data produced from low-latitude Sakmarian brachiopods, and in line with data from high-latitude Australian brachiopods (Korte et al., 2008, PPP). Intraspecimen δ18O variation is significant, with ranging from 1.1‰ to 2.1‰. These regular, cyclical trends are not found in the concurrent δ13C data, which are not significantly variant and average ~4.2‰.

These seasonal records characterize variations in local seawater geochemistry and temperatures. If a constant δ18Ow of -1‰ is assumed, the seasonal paleotemperature range averages ~ 6 °C, with an average minimum paleotemperature of ~8.4°C and an average maximum paleotemperature of 14.6 °C. The δ18O ranges in these brachiopods are less than that of the Permian bivalve Eurydesma from Australia (Ivany and Runnegar, 2010, Geology), but seasonal changes in salinity due to fresh water mixing and melt water may have amplified that δ18O range.